UCD

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Authors

Kerrigan, NJ; Dunne, EC; Cunningham, D; McArdle, P; Gilligan, K; Gilheany, DG; ;

Year

2003

Month

March

Journal

Tetrahedron Letters

Title

Studies in the preparation of novel P-chirogenic binaphthyl monophosphanes (MOPs)

Status

Published

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Issue

Start Page

8461

End Page

8465

Abstract

Several routes to P-chirogenic binaphthyl monophosphanes (MOPS) and their derivatives were investigated. Palladium catalysed coupling gave access to a new class of P-chirogenic phosphane oxides from which the phosphane can be obtained by reduction. Substituents on phosphorus strongly influence the efficiency of the P-C coupling reaction, which is only slightly stereo selective. (C) 2003 Elsevier Ltd. All rights reserved..

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