Publication Type
Publication Type
Peer Reviewed Journal
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Authors
Daly, AM; Gilheany, DG; ;
Year
2003
Month
January
Journal
Tetrahedron Asymmetry
Title
The synthesis and use in asymmetric epoxidation of metal salen complexes derived from enantiopure trans-cyclopentane- and cyclobutane-1,2-diamine
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Published
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Volume
14
Issue
1
Start Page
127
End Page
137
Abstract
A complete synthesis of enantiopure trans-cyclopentane-1,2-diamine and trans-cyclobutane-1,2-diamine is described. These diamines have been used as components of novel chiral salen ligands whose chromium and manganese complexes were then evaluated as oxygen transfer agents in the asymmetric epoxidation of alkenes. (C) 2003 Elsevier Science Ltd. All rights reserved..
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