Publication Type
Publication Type
Peer Reviewed Journal
Mandatory Citation Fields
Authors
Higham, LJ,Kelly, PG,Corr, DM,Muller-Bunz, H,Walker, BJ,Gilheany, DG;
Year
2004
Month
March
Journal
Chemical Communications
Title
A novel azulene synthesis from the Ramirez ylide involving two different modes of its reaction with activated alkynes
Status
Published
Times Cited
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CRYSTAL-STRUCTURE SUBSTITUTED AZULENES CYCLOPENTADIENYLIDE DERIVATIVES CONVENIENT RING
Volume
-1
Issue
6
Start Page
684
End Page
685
Abstract
The Ramirez ylide undergoes electrophilic substitution with acetylenedicarboxylates to form Z and E adducts. The latter can react by cycloaddition with another equivalent of the alkyne to provide a new route to novel tetra-substituted azulenes, which show interesting bond localisation and crystal packing effects.
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ISBN / ISSN
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URL
DOI Link
DOI 10.1039/b316759c
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