Publication Type
Peer Reviewed Journal
Mandatory Citation Fields
Kamalraj V. Rajendran and Declan G. Gilheany
2012
February
Chemical Communications
Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride
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48
817
819
A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.
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